Influence of iron, phosphate, and silicate on arsenic removal from groundwater using a low-cost ceramic filter.

The ceramic filter amended with iron (Fe) has proven to be a potential low-cost method for arsenic (As) removal from groundwater. The presence of Fe, phosphate (P), and silicate (Si) significantly affects the As removal efficiency of the ceramic filter, which has not been passably investigated. The present research aimed to examine the effect of Fe, P, and (or) Si presence as single or in combination on As (III) removal from synthetics groundwater by a low-cost iron amended ceramic filter (IACF). Laboratory-scale filtration experiments at different compositions of Fe, P, Si, and As (III) were conducted by the IACF fabricated with a ceramic candle and iron netting box. Fe (II) in synthetic groundwater positively impacted As (III) removal. At a concentration of 2 mg/L of Fe (II), the As levels in the effluent decreased to less than the maximum contamination level (MCL) of 50 µg/L. Groundwater P concentration needed less than 3 mg/L or Si concentrations required less than 35 mg/L to effectively reduce As (III) to below the MCL at 5 mg/L of groundwater Fe (II). The cumulative effect of P and Si on As removal was found to be more significant than distinct contributions. The presence of 2 mg/L P and 35 mg/L or higher Si in the groundwater cumulatively reduced the As removal performance from 92% to 63%, and the MCL was not met. The negative impact of P and Si on As (III) removal followed the order of (P + Si) > P > Si. P competed with As for adsorption sites during the process, while Si inhibited the Fe release and floc formation, significantly reducing As removal performance. The study findings can potentially contribute to optimizing IACF as a low-cost method for As removal from groundwater.

Comparative evaluation of low-cost ceramic membrane and polymeric micro membrane in algal membrane photobioreactor for wastewater treatment.

Algal-bacterial membrane photobioreactor (AMPBR) is proven as a highly energy-efficient process for treating domestic wastewater. This study compared the application of polymeric micro-membrane (PMM) and a low-cost ceramic membrane (LCM) to the AMPBR process for treating domestic wastewater with low and high organic pollution levels. Experiments were conducted over 57 days using two PMM-AMPBRs and two LCM-AMPBRs, operating on a 12-h dark/light cycle in a continuous mode. Simulated wastewater containing varying levels of chemical oxygen demand (COD) was fed to reactors for a consistent hydraulic residence time (HRT) of 7 d and a flux rate of 100 L/m2/d. PMM and LCM-AMPBRs demonstrated efficient wastewater treatment capabilities, achieving COD removal rates exceeding 94% and 95% for high and low COD loadings, respectively. PMM-AMPBR achieved 54.1% TN removal at low COD loading, while LCM-AMPBR achieved 57.2%. These removal efficiencies decreased to 45.6% and 47.0% under high COD loading. Total Phosphorus (TP) removal reached 29-33% for PMM-AMPBRs and 21-24% for LCM-AMPBRs, irrespective of COD loading. LCM-AMPBRs showed significantly lower fouling frequency than PMM-AMPBRs. The biomass production rate decreased with increasing COD loading and achieved 40 mg/L/d at low COD loading for both AMPBRs. Net energy return (NER) values for both AMPBRs were close to 0.87, indicating them as energy-efficient processes. Considering the cost-effectiveness and comparable performance, LCM-AMPBR could be a viable alternative to PMM-AMPBR for wastewater treatment, particularly under low COD loading conditions.

Experimental and computational analyses for advanced wastewater treatment by volcanic rocks.

Treating and reusing wastewater is a promising alternative for the water shortage problem. The advanced treatment of such water can provide a good source for plant irrigation and other applications and reduce the demand for the available freshwater resources. This alternate is highly recommended for arid and semi-arid counties. In this research, volcanic rock (VR) is introduced as an advanced and low-cost treatment option for wastewater. The volcanic rock was adopted as an adsorption tool for removing impurities from the secondary treated wastewater effluents. The study relies on experimental work on a lab scale. Many parameters were investigated such as loose and compacted layered samples, and pretreated methods for the rocks including soaking in clean water or heating for different temperatures. Simulation work also was adopted to validate the experimental results. The study results showed a decline in most physiochemical properties of wastewater after adding VR compared with the control sample. A notable removable for the measurements of the biological oxygen demand and chemical oxygen demand (COD) from wastewater in the presence of VR was observed, which may introduce it as a tool for the advanced treatment of wastewater. The numerical results depicted the experimental data and reflected the effectiveness of the VR-based geomaterial filter for the treatment of wastewater. PRACTITIONER POINTS: Prewashing process for volcanic rock (VR) exhibited an improvement in its removal efficiency ranged between 18% to 98% as for TDS and removal of NO3 - , respectively. Heating samples does not improve the removable properties of VR. A notable removable for biological oxygen demand and COD by 96% and 99%, respectively, for some cases from wastewater, may introduce the VR as a tool for advanced treatment of wastewater. The numerical test results are in consistent with the experimental behavior of the VR and reflect the effectiveness of the VR-based geomaterial filter for the treatment of wastewater.

Spatiotemporal variations of DOM components in the Kushiro River impacted by a wetland.

Dissolved organic matter (DOM) has been recognized as a serious water quality problem in natural water bodies receiving pollution loads from point and nonpoint sources. The present study investigates the spatiotemporal variability of DOM composition in the Kushiro River and its tributaries (Eastern Hokkaido, Japan) impacted by the Kushiro wetland. Water samples were collected in the wet and dry seasons from several locations of the river and analyzed for DOM characteristics by UV-visible and excitation-emission matrix fluorescence spectroscopy techniques and by developing water quality index. Rather than the spatial effect, significant seasonal impacts on DOM pollution in the Kushiro River were observed. Overall concentrations of DOM decreased during the dry season. The increase of specific ultraviolet absorbance in the dry season indicated an increasing trend of humification, aromaticity and molecular weight of DOM. Five fluorescent peaks, including peaks A, C, M, B, and T were predicted by EEM spectra. Peaks A and C were found to be the most dominating peaks in both the seasons and indicated enrichment of humic-like matters in river water. The intensities of poly-aromatic humic substances as well as DOM components of microbial origin increase in the wet season and proteins like autochthonous DOM increase during the dry season. The study recognized the contribution of freshly produced DOM component by the decomposition of wetland plants in wet season and effect of snowfall in the dry season. Analysis of three fluorescence indices revealed that the river water primarily contains terrestrially dominated DOM. A significant impact of the adjacent WWTPs and wetland to the river water DOM were also observed. The water quality index of river water DOM showed low to medium levels of DOM pollution in the Kushiro River.

Experimental and numerical study for seawater intrusion remediation in heterogeneous coastal aquifer.

The contamination of fresh groundwater by saltwater intrusion (SWI) becomes a worldwide alarming problem, which threatens all countries depending on groundwater abstraction from coastal areas. Various control and treatment strategies have been suggested to prevent SWI. The construction of subsurface physical barriers is one of the most practical implementation methods to prevent SWI. In this work, the use of subsurface dam as a remediation and protection tool was investigated in a heterogeneous aquifer via lab scale experiments and numerical simulation. The experiments depended on a novel automated imaged analysis method for SWI measurements. Glass beads of different grain sizes were used in sandbox experiments. The simulation works adopted the SEAWAT code for validation of the experimental results and making numerical sensitivity analyses for affecting parameters. Results proved the significant impact of using sub water dams with heterogonous aquifers. The remediation impacts of the dam was captured clearly in preventing and backwashing of the existed SWI. The results revealed also that the heterogeneous aquifers with high permeability in the bottom boundary behave closer to the homogenous aquifers in SWI than those having low hydraulic conductivity in the bottom. Sensitivity analyses results showed that the closer dam to seawater boundary led to the quicker and more effective backwashing process. Results exhibited also that the dam height with 50% of the aquifer dam has the ability to hold the seawater so long as the hydraulic gradient is high and dams with 67% of aquifer height prevent the saltwater intrusion completely.

Seawater Intrusion Impacts on the Water Quality of the Groundwater on theNorthwest Coast of Oman.

The groundwater aquifer in the coastal region of the northwest of Oman has been used extensively since the early 1980s for agricultural, industrial and municipal purposes. The over pumping of this reservoir has led to the intrusion of seawater and therefore to the deterioration of the groundwater quality. In this study, an investigation was carried out in the southern part of this region to identify the quality of groundwater, to understand the main sources of groundwater mineralisation, and to check the suitability of groundwater for drinking and irrigation. The spatial distributions and temporal variations of groundwater level and electrical conductivity were studied for the period from 1982 to 2005 using data collected from 225 wells. In addition, groundwater samples were collected recently in 2012 from eight wells and analysed for pH, EC, and major ions to understand the sources of dissolved ions and assess the chemical quality of the groundwater. The study area was divided into two strips parallel to the coastline, A and B, located in the discharge and recharge parts of the aquifer, respectively. Results showed a significant increase in the degree of water mineralisation in the direction of south to north following the regional flow direction. Results showed also that the groundwater in the last area could be used for irrigation with little danger of exchangeable sodium while this aquifer is unsuitable for irrigation in the discharge area because it presents a very high salinity hazard.

Effectiveness of novel and traditional treatments on the performance of incinerator bottom ash waste.

Management of natural aggregate resources has become one of the most important challenges in construction, especially for high demand applications such as roads. Incinerator bottom ash (IBA), which is produced from burning domestic waste, has been considered a useful solution to the shortage of natural resources. In this research, IBA was mixed with limestone to produce an acceptable blend for use as a road foundation layer. Novel and traditional additives were adopted to improve the mechanical properties of IBA blends. The study focused on the treatment effect of additives on the mechanical characteristics of IBA blends under monotonic and cyclic triaxial stresses. The investigation evaluated fundamental material properties, including resilient modulus, initial Young's modulus and Poisson's ratio. Two nonlinear empirical models were adopted to depict the experimental resilient modulus results of the IBA blends. An approach has been proposed to predict realistic and representative values of resilient modulus for the material. In addition, a new relationship has been established between Young's modulus, resilient modulus and Poisson's ratio. Triaxial test results revealed that additives are more efficient with the control limestone blend than with the IBA blends. Novel additives, such as enzyme I and silica fume, produced a noticeable improvement in IBA properties in comparison to traditional additives.

A lysimeter experimental study and numerical characterisation of the leaching of incinerator bottom ash waste.

Incinerator bottom ash (IBA) is a residual produced from incinerating municipal solid waste. In the past, IBA presented a big waste disposal problem; however, various recycling approaches have been adopted in recent years to mitigate this problem, as well as to provide a useful alternative to using primary aggregate resources. The use of IBA as an alternative to conventional aggregates in different civil engineering construction applications helps to conserve premium grade aggregate supplies; however, when IBA is in contact with water in the field, as a consequence of precipitation events or changes in water table, elements, such as salts and heavy metals, may be released to the soil and ground water. In this work, IBA waste was mixed with limestone aggregate to produce a blend with acceptable mechanical properties and minimum environmental risks for use as road foundation. The study focused on evaluating potential environmental impacts of some constituents, including sulphate, chloride, sodium, copper, zinc and lead in IBA blends using a lysimeter as a large scale leaching tool. Moreover, a specific scenario simulating field conditions was adopted in the lysimeter to assess the potential impact of changing conditions, such as IBA content in the blend, liquid to solid ratio (L/S) and pH value, on long-term release of heavy metals and salts. Then, numerical modelling was used to predict the release of the aforementioned constituents from IBA based on initial measurement of intrinsic material properties and the kinetic desorption process concept. Experimental results showed that zinc and lead were released in very low concentrations but sodium and sulphate were in high concentrations. The control limestone only blend also demonstrated low release concentrations of constituents in comparison to IBA blends, where constituent concentrations increased with increase in IBA content. Experimental results were compared with numerical results obtained using a non-equilibrium desorption model. Good agreement was found between the two sets of data.